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  • Apatite is a group of phosphate minerals, usually referring to hydroxylapatite, fluorapatite and chlorapatite, named for high concentrations of OH−, F−, Cl− or ions, respectively, in the crystal. The formula of the admixture of the four most common endmembers is written as Ca10(PO4)6(OH,F,Cl)2, and the crystal unit cell formulae of the individual minerals are written as Ca10(PO4)6(OH)2, Ca10(PO4)6(F)2 and Ca10(PO4)6(Cl)2. Apatite is one of a few minerals produced and used by biological micro-environmental systems. Apatite is the defining mineral for 5 on the Mohs scale. Hydroxyapatite, also known as hydroxylapatite, is the major component of tooth enamel and bone mineral. A relatively rare form of apatite in which most of the OH groups are absent and containing many carbonate and acid phosphate substitutions is a large component of bone material. Fluorapatite is more resistant to acid attack than is hydroxyapatite; in the mid-20th century, it was discovered that communities whose water supply naturally contained fluorine had lower rates of dental caries. Fluoridated water allows exchange in the teeth of fluoride ions for hydroxyl groups in apatite. Similarly, toothpaste typically contains a source of fluoride anions. Too much fluoride results in dental fluorosis and/or skeletal fluorosis. Wikipedia

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