Filter options:

Freebase Commons Metaweb System Types /type

Object is not asserted on this topic.

Freebase Commons Common /common

  • The Meerwein–Ponndorf–Verley reduction in organic chemistry is the reduction of ketones and aldehydes to their corresponding alcohols utilizing aluminium alkoxide catalysis in the presence of a sacrificial alcohol. The beauty in the MPV reduction lies in its high chemoselectivity, and its use of a cheap environmentally friendly metal catalyst. The MPV reduction was discovered by Meerwein and Schmidt, and separately by Verley in 1925. They found that a mixture of aluminium ethoxide and ethanol could reduce aldehydes to their alcohols. Ponndorf applied the reaction to ketones and upgraded the catalyst to aluminium isopropoxide in isopropanol.